• 0 Posts
  • 11 Comments
Joined 3 years ago
cake
Cake day: June 27th, 2023

help-circle
  • Actually, this isn’t quite as simple as a dew catcher. For MOFs specifically, there’s a fundamental physical chemistry principle going into it which is able to capture the water. At the molecular level, the MOF structures are super porous, which allows the water in the air to become trapped inside. The difference between that and dew catchers is dew catchers aren’t able to actually harvest gasseous H2O. They only harvest what is able to be deposited in liquid form. Water from air technology is a real thing, and there are at least decades of research on it.

    You may have some experience with a slightly different form of vapor harvester, silica gel packets! Those use a chemical based methodology to bond with water molecules in the air instead. There are two major difference between those and MOFs is that MOFs are reusable, and silica gels are not quite reusable. The other difference is in the holding capacity of MOFs. They can hold significantly more water than silica based gels.

    The economics of the emerging MOF field is definitely uncompetitive in it’s current form. The current price to performance ratio isn’t something that can currently compete with existing technologies, whether it is trucking water, or desalination. The industry knows this, and knows it must get the price down to competitive levels. However the reason why it is nobel prize winning this time is that now the performance is in a ballpark where it could be commercially viable. It would be more environmentally friendly to setup some solar water harvesters one time, rather than to be constantly trucking or piping in water from elsewhere. Extremely remote communities would be more self reliant if they don’t have to be paying exorbitant amounts of money each time for new water delivery.



  • As for local or regional scales, yes there could be impacts. I’m not quite as well versed in how trees affect the environments, but I suspect a local water-from-air farm would have some impacts on a local scale. If we had some data on how redwood trees absorb based on the different environmental conditions, I could run some numbers to figure out the differences and see how it would be affected.

    Agreed on the impacts though, this isn’t a zero impact technology, but compared to the direct competitors it is trying to replace (groundwater harvesting or desalination), it is an improvement. A mindset I like to apply is that humanity will need water regardless of how they get it. New technologies should provide a solution that is lower impact, along with a financial incentive (cost).



  • MOF behaves like a sponge, but wouldn’t feel like a sponge. Squeezing it would be nice, and could definitely eliminate the hassle of having to heat it up.

    As for the energy, the thermodynamics of dehumidification basically requires an external energy source. To cool the air, you have to have a heat engine which removes the active ambient thermal energy out of a system. Such a system would look like a traditional dehumidifier hooked up to solar panels. The issue with that is the associated capital expenditure costs to build up such a system, as that already costs significantly more than “some random metal sponge” (assuming we could make it at scale).

    For now, the only ways to cool the air down would be to use traditional refrigeration techniques, or peltier coolers. Peltier coolers are super inefficient, and traditional heat pumps require alot of energy. When in a low humidity environment, the coefficient of performance for heat pumps goes way down because the outdoor temperature could be very high, and the humidity very low. To reduce the air temperature to below dew point would mean cooling the air to near 0c, which is pretty much putting a freezer in a desert.

    Solar energy is free, but absorbing it and converting it into useful work takes a good bit of engineering effort to make happen. What MOFs and similar materials can take advantage is being able to be left out in the sun like a sun dried tomato and covered in a black painted cover. Couldn’t be simpler!



  • Technically yes! To put it in perspective, there’s about 2.5kg of water in the atmosphere per m^2 of earth surface area. If you put enough panels across the earth, you could probably do a decent job at taking some of the water out of the air.

    We have to look at another factor affecting the water in the air. As we take water out of the air, it’s not really a finite resource. Most water in the air generally comes from the sun evaporating the oceans. If we take the water out of the air, the sun will put the water back. There’s always a balance of humidity and quantity evaporated. When the humidity is lower, the sun would have an easier time evaporating more water due to the osmosis of the water from the source (ocean) going into the air. Osmosis is a kind of log graph, so even if the humidity is lower, the exponential tail means the solar evaporation and humidity pretty much balances out at the end of the day.

    It’s similar thing to taking water from a river. If we take all the water from a river, can we dry up downstream? Yes! But considering the height of the atmosphere, it’s like standing at the edge of the river trying with a bucket and trying to scoop everything up. Unless these water-from-air harvesters can reach all the way to the clouds, we probably won’t dry anything up.



  • MOFs and other types of materials are actually a highly well researched topic. They’ve been around for decades! However in the current state of things, it’s kinda like battery technologies we see. It depends on the scale of manufacturing that these researchers can scale up production to.

    Alot of time, the processes researchers do to manufacture small batches to produce a small prototype don’t work well when scaling up. The team I was working with had lots of trouble with it, but eventually settled into producing batches that would fill approximately a construction bucket worth at a time. Not a huge amount, but definitely a starting spot. It not mpossible to assembly line something like a millions of buckets a day, but at the same time your manufacturing costs go up alot.

    There are many different competing kinds of water-from-air materials. These researchers use MOFs, but since they use metals, the cost to manufacture goes up significantly. Polymer based materials are a bit more “secret sauce” depending on the formulation, but they’re simpler in the sense you can use specific kinds of salts. The cost difference is something like 10x, so MOF really needs to produce 10x more value, otherwise it’s not worth it.

    Since water is such a commoditized product, commercial prices are somewhere around a few dollars per cubic meter of water. When you design something that has to compete with existing products, you have to have a cost at, or less than existing prices. Either your panel has to be super cheap, or your water production has to be off the charts.

    Let’s say a commercial water-from-air solar farm lasts for 30 years. Each day, 1sqm of panel produces 1 cubic meter of water. You’re only selling that water for $3 (approximate commercial rates). Over the lifetime of the panel, your income is 30years * $3 = $32850. It’s a big number! A realistic current figure for water production at best would hit 0.01 cubic meters of water. Holey cow! Now you’re actually making 1% of our original target, which is 3 cents per day, or $330 over it’s lifetime.

    Selling anything that’s 1m^2 for only that price point is a crazy feat to achieve. I designed a number of systems that would try to enable that, but you must also factor in everything including installation and maintenance costs.

    There’s billions of dollars thrown around to invest in these technologies. The only thing stopping it are the unit economics. You have to compete in an industry that is centuries old. But these can succeed, they can easily replace every single water filter in the world.


  • There’s two impacts these panels could have. There’s the solar irradiation aspect, and the air humidity aspect of them.

    In the solar irradiance balance, you have a net energy in, most of which goes directly to heating the ground. A panel would aim to absorb as much as that energy as you can, most of which would go towards a phase change of the material to release the water bonds. MOFs are extremely clean in terms of their re-usability, and don’t release any other compounds into the steam when released. Think of it like a condensation system, but without having to collect any water from any ground based source.

    The air humidity is the other balance. In theory you could “absorb all the water out of the air”. In most business cases, these need to be deployed to more coastal regions, not literally smack in the middle of the desert. But in such cases, the atmosphere is highly dynamic and more or less equalizes total air water content in a certain microclimate. It makes it very renewable since the sun evaporates massive amounts of water from water bodies, which can be returned via either rain, or through water harvested through water-from-air chemistry.

    The industry will want to buy water regardless of where they are, so when evaluating technologies, these provide much lower impact to the environment than any existing groundwater based system.


  • I used to work for a company making a similar device, the chemistry behind the technology is actually a well researched topic, and there are many kinds of various chemistries that can achieve a similar effect. Silica gel packets are the most common, a cheap solution that extracts moisture from the air, but is non-reusable.

    These MOF compounds are useful because they have a fundamentally different method of collecting the water molecules. The framework traps the molecules inside, which can be later released with heat. Thermal solar power is free, but does require careful management of the rest of the device such that the material can get hot enough (usually around 100c), which also providing another surface to condense the vapour. I spent alot of time designing and testing such panels. They do work! I can post pictures of fishtanks of water later.

    There truly couldn’t be much of a downside to these technologies. The real alternative is desalination, which produces hyper concentrated salt pools, or well water extraction, which is also bad…

    The reason these technologies is usually due to the cost effectiveness to produce the material, and to build the enclosure around the material. The panels have to scale very large to get any reasonable about of solar power, plus the condensing and collecting mechanisms also add weight and cost. Water is not an expensive product, so at the end of the day, the economics don’t always work out favourably.

    Happy to answer any questions about the technology.